Catalytic pyrolysis is an effective way to use lignin resource.A ternary metal?organic framework (MOF) precursor was synthesized by using the solvothermal method, and then the perovskite Ca1-x Nd x CoO3 (CNC?x) was prepared by controllable calcination.The performance of the perovskite for catalyzing bagasse lignin (BL) pyrolysis and regeneration was investigated,and the distribution law of the compositions of gaseous and liquid phase products was analyzed. The results show that CNC?0.3 calcined at 800 ℃ shows excellent performance in catalyzing BL pyrolysis.Under a temperature of 200~500 ℃,the pyrolysis activation energy is reduced from 64.24 kJ/mol to 58.92 kJ/mol.Compared with BL pyrolysis,the yield of gaseous phase products decreases,while that of solid phase products increases.The yield of liquid phase products is increased from 15.11% to 17.94%,and the liquid phase products are mainly aromatic oxygenated chemicals including phenols,guaiacols,syringols,and phenyl ethers.The total selectivity of aromatic oxygenated chemicals is 11.0% higher than that under pyrolysis.After five times of regeneration,CNC?0.3 still shows satisfactory structural and catalytic stability.
